Thursday, September 29, 2011

Calomel Electrode ( Mercury-Mercurous electrode)- Secondary Reference Electrode

Calomel Electrode 
Standard Hydrogen electrode is a primary reference electrode, the usage is  difficult as it has many disadvantages. Other electrodes with constant electrode potential are called as secondary reference electrodes. Calomel electrode and Silver-Silver chloride electrodes are examples for such reference electrodes.


Calomel electrode cell representation is
Hg | Hg2Cl2 (s) | KCl or Hg , Hg2Cl2 (s) , KCl.  
Calomel electrode acts as an anode or cathode electrode depending on the nature of the other electrode.



5 comments:

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  2. When calomel electrode acts as anode??

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    Replies
    1. When the potential of other electrode is more than calomel electrode

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